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Forever Chemical Discovery Can Aid Drinking Water Treatment

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Forever Chemical Discovery Can Aid Drinking Water Treatment

Context:

Scientists discovered a new chemical process to aid in the treatment of “forever chemicals” or Poly- and perfluoroalkyl substances (PFAS) in drinking water.

 

More on News: 

  • University of California, Riverside scientists discovered a chemical process that leverages high salt levels in wastewater to catalyze the breakdown of PFAS by targeting the strong fluorine-to-carbon bonds.
  • This method is highly efficient due to the use of short-wavelength UV light, which is effective even in the presence of other chemicals in the wastewater.
  • It destroys both long-chain and hard-to-remove short-chain PFAS that traditional methods can’t handle.
  • The discovery is beneficial for municipal and private water providers using ion exchange technology
    • As this technology separates PFAS from water but generates brine waste.

 

 

Forever Chemical Reaction

 

Per- and polyfluoroalkyl substances (PFAS)

  • Per- and polyfluoroalkyl substances (PFAS), commonly known as “forever chemicals,” do not break down for hundreds or thousands of years.
  • They are the most persistent synthetic chemicals, used in consumer products since the 1950s
  • Their strong carbon-fluoride bonds, among the strongest in organic chemistry, make PFAS highly resistant to degradation and very mobile in water.
  • They can seep into rainwater, soil, sediment, and drinking water, posing significant risks.
  • PFAS are also listed in the Stockholm Convention, highlighting the global recognition of the environmental and health risks posed by these chemicals.
  • Health Impacts: 
      • Exposure to PFAS is linked to liver damage, thyroid disease, obesity, fertility issues, and cancer.
      • People can come into contact with PFAS through contaminated food, consumer products, and drinking water.
  • Economic and Environmental Costs:
      • Annual Cost to Society is estimated at $17.5 trillion.
      • Pollution, including PFAS contamination, is ranked as the 10th most pressing threat by the World Economic Forum’s Global Risks Report 2024.
  • Potential solutions: 
      • PFAS can be broken down into less harmful substances using sodium hydroxide (lye), a cost-effective chemical widely used in soap manufacturing.
      • The most prevalent approach for eliminating PFAS is high-temperature incineration. 
        • PFAS can be fully decomposed at approximately 1,500 degrees Celsius (2,730 degrees Fahrenheit), but this method is energy-intensive and necessitates specialised incinerators. 
      • Although effective treatment options exist, the lack of sufficient incineration facilities capable of processing PFAS poses a major challenge.

 

PFAS Sources

 

Regulatory Actions: 

  • United States: The US Environmental Protection Agency has set a limit of four parts per trillion for PFOA and PFOS in drinking water.
  • European Commission (EC): EC committed to phase out all PFAS, allowing their use only if they are proven to be irreplaceable and essential to society.
  • Netherlands, Germany, Denmark, Sweden, and Norway submitted a proposal to European Chemicals Agency (ECHA) to restrict use, import and production of PFAS substances.

 

 

Stockholm Convention:

  • Aim: To protect human health and the environment from persistent organic pollutants (POPs).
  • Characteristics of POPs:
      • Remain intact in the environment for extended periods.
      • Become widely distributed across regions.
      • Accumulate in the fatty tissues of living organisms.
      • Harmful to humans and wildlife.
  • India’s Involvement
      • Ratification: India ratified the Stockholm Convention in 2006.
      • Opt-Out Provision: As per Article 25(4), India maintains a default “opt-out” stance
      • It means that amendments to the convention’s annexes do not apply to India unless it explicitly agrees.

 

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